Supercritically Foamed Thermoplastic Polyurethane

Title: LOW DENSITY FOAM, MIDSOLE, FOOTWEAR, AND METHODS FOR MAKING LOW DENSITY FOAM

 Number/Link: WO2015/017088

Applicant/Assignee: Nike

Publication date: 5-02-2015

Gist”: TPU blown with supercritical CO2 and/or N2

Why it is interesting: This case relates to foamed TPU (or EVA) with densities down to 150 kg/m³. The low density is accomplished by the combination of a conventional physical blowing agent and a supercritical fluid, specifically supercritical CO2 or N2 or a combination of these. The conventional blowing agent is incorporated into the polymer pellets before these are added to the extruder while the supercritical fluid is added to the molten polymer through a port in the extruder barrel.  The material is then extruded or injection moulded. Nike have filed two more patents on this technology: WO2015/017089 and WO2015/017090.

Nike shoe with EVA midsole

Nike shoe with foamed thermoplastic midsole

PPE-Filled Rigid Foams

Title: RIGID FOAM AND ASSOCIATED ARTICLE AND METHOD

 Number/Link: WO2015/012989

Applicant/Assignee: SABIC

Publication date: 29-01-2015

Gist”: Rigid polyurethane foams containing polyphenylene ether particles

Why it is interesting: This invention is about rigid PU or PIR (polyisocyanurate) foams containing up to 25% w/w on the total composition of poly(2,6-dimethyl-1,4-phenylenether) particles.  The particles have a mean particle size of about 6 µm and are prepared by jet milling a commercial grade of PPE powder. The resulting foams are said to have reduced flammability and water absorption.  This is the second patent application that SABIC files on PPE-PU hybrids or combinations.  An interesting development but it is hard to believe that these ideas are practical and economical.

poly(2,6-dimethyl-1,4-phenyleneether)

poly(2,6-dimethyl-1,4-phenylene ether)

Cross-Linked Melt-Spun Polyurethane Fibers

Title: ISOCYANATE PREPOLYMER COMPOSITION AND CROSSLINKED POLYURETHANE PREPARED THEREFROM

 Number/Link: WO2015/007731

Applicant/Assignee: BASF

Publication date: 22-01-2015

Gist”: Melt spinning a TPU – prepolymer blend.

Why it is interesting: Crosslinked polyurethane fibers are produced by melt-spinning a thermoplastic polyurethane which is melt-blended with a specific isocyanate prepolymer composition.  The prepolymer composition is a mixture of a polymeric MDI and the reaction product of a polyester polyol and an excess of 4.4′-MDI. The polyester polyol is prepared from adipic acid together with 2-methyl-1,3-propanediol (MPdiol) and/or trimethylolpropane. The prepolymer composition is characterized by its low viscosity (probably due to the use of the branched polyester).  The crosslinked fibers show an improved tensile set and temperature resistance.

Polymeric MDI

Polymeric MDI

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