All posts tagged PDMS

Thermoplastic PU-PDMS Copolymer

Patent Title: THERMOPLASTIC POLYURETHANE

Number/Link: WO2019/016313 (German)

Applicant/Assignee: BASF

Publication Date: 24 January 2019

“Gist”:  Thermoplastic polyurethane comprising OH-ended poly(dimethylsiloxane).

Why it is interesting: The invention relates to thermoplastic polyurethanes prepared from diisocyanate, polyether or polyester diol and a difunctional isocyanate-reactive polysiloxane.  The materials are said to have improved “haptic”-, hydrophobicity- and tensile properties while retaining the processibility of TPU and are useful for ‘on-body’ applications like wristbands. In the examples both 4,4′-MDI and HDI are used together with chain extenders, polyTHF, BDO-HDO adipate and EO capped PDMS to prepare TPUs ranging from 55 to 95 Shore A.

pdms-eo

EO-capped PDMS

Advertisement
Leave a comment
by Gerhard Bleys on January 25, 2019  •  Permalink
Posted in Thermoplastics
Tagged , , , , , , , , , ,

Posted by Gerhard Bleys on January 25, 2019

https://purpatents.com/2019/01/25/thermoplastic-pu-pdms-copolymer/

Phosgene-Free Polyisocyanate with PDMS Backbone

Patent Title: MULTI-FUNCTIONAL CARBAMATE HAVING SOFT-SEGMENTS, POLYISOCYANATE OBTAINED VIA SUBSEQUENT NON-PHOSGENE SYNTHESIS METHODS, URETHANE PREPOLYMER AND ELASTOMERIC URETHANE HAVING SOFT-SEGMENTS DERIVED THEREFROM, AND PREPARATION METHOD THEREOF

 Number/Link: US20180186918

Applicant/Assignee:  Great Eastern Resins Industrial

Publication date: 5 July 2018

“Gist”: Biscarbamate with PDMS softblock backbone is heat-cracked into diisocyanates

Why it is interesting: The invention relates to isocyanate-capped “softblock” siloxanyl prepared without using phosgene and polyurethanes derived therefrom. The invention is accomplished by reacting relatively high MW polydimethylsiloxanediamines with diphenylcarbonate.  The resulting biscarbamate is heated under reduced pressure to produce the diisocyanate and to remove the phenol by-product.  The isocyanates can be reacted with polyols and/or chain extenders to produce highly hydrophobic polyurethanes with low surface tension and good chemical resistance.

biscarbamate

Biscarbamate with PDMS backbone

 

Leave a comment
by Gerhard Bleys on July 9, 2018  •  Permalink
Posted in Elastomers, Isocyanates and Prepolymers
Tagged , , , , , , , ,

Posted by Gerhard Bleys on July 9, 2018

https://purpatents.com/2018/07/09/phosgene-free-polyisocyanate-with-pdms-backbone/

PU-FPOSS Coating Compositions

Title: ICE ADHESION REDUCING PREPOLYMERS AND POLYMERS

Number/Link: US20170204291

Applicant/Assignee: Boeing

Publication Date: 20 July 2017  (published as PCT)

“Gist”: Ice repellent polyurethane coatings are prepared by incorporating F-POSS prepolymers

Why it is interesting: The invention is about coated surfaces that show reduced ice formation and/or adhesion. This is accomplished by incorporating fluorinated polyhedral oligomeric silsesquioxanes (F-POSS) into the composition. OH-functional F-POSS is prepared as per the scheme below, which is then reacted with polyisocyanates to prepare an NCO-functional F-POSS prepolymer.  The prepolymer can then be used in PU coating compositions, or reacted with amino-functional PDMS compounds and used as an additive in coating compositions.
It is believed that the F-POSS particles interfere with H-bond formation of ice to the coated surface.  Ice repellent surfaces are particularly useful for aircraft, wind turbines, cooling equipment and the like.

Synthesis of OH-functional trifluoropropyl POSS

Leave a comment
by Gerhard Bleys on July 24, 2017  •  Permalink
Posted in Adhesives-Coatings, Isocyanates and Prepolymers
Tagged , , , , ,

Posted by Gerhard Bleys on July 24, 2017

https://purpatents.com/2017/07/24/pu-fposs-coating-compositions/

« Older Posts

  • Pages

  • Categories

  • Enter your email address to follow this blog and receive notifications of new posts by email.

    Join 1,089 other subscribers

  • Follow Innovation in PU on Twitter

%d bloggers like this: