Novel Chain Extenders

Patent Title: METHOD OF PRODUCING FIVE-CARBON RING-CONTAINING COMPOUND AND FIVE-CARBON RING DERIVATIVE-CONTAINING POLYURETHANE, AND FIVE-CARBON RING DERIVATIVE-CONTAINING POLYURETHANE

Number/Link: US2019/0048123

Applicant/Assignee: CHUNG SHAN INSTITUTE OF SCIENCE AND TECHNOLOGY

Publication Date: 14-February 2019

Gist”: Novel chain extenders are derived from dicyclopendadiene (DCPD)

Why it is interesting: DCPD is a by-product of ethylene production by steam cracking of naphta.  It is produced in large quantities and it makes sense to search for new applications.  According to this invention, the compound shown below can be prepared by first ‘degrading’ DCPD to cyclopentadiene, followed by reaction with phenol to produce 4-(cyclopent-2-enyl)phenol which is then converted to 4-cyclopentenylphenol (translocation of the double bond).  The cyclopentenylphenol is then reacted with phenol followed by reaction with ethylene carbonate to produce the chain extender. In an example the chain extender is reacted with a 4,4′-MDI prepolymer in solvent.
Clever chemistry and an interesting compound, but its usefulness remains to be shown.

extender

Chain extender according to the invention

Fiber Reinforced TPU Composites

Patent Title: THERMOPLASTIC POLYURETHANE MATRIX RESIN

 Number/Link: WO 2018/104145

Applicant/Assignee:  Henkel

Publication date: 14 June 2018

Gist”: TPU based on a vicinal alkane diol together with an alkoxylated aromatic diol can be used as matrix material in a fiber composite

Why it is interesting: According to this invention a thermoplastic polyurethane with a high Tg (pref. >80°C) and a high stiffness (>1GPa) can be prepared from a short chain, sterically hindered, vicinal diol (e.g. 1,2-propanediol or 2,3-butanediol), an alkoxylated aromatic diol (e.g. alkoxylated bisphenol A or F) and an aromatic diisocyanate (e.g. 4,4’MDI) pref. mixed with some high functionality isocyanate (e.g. polymeric MDI) to control branching an molecular weight. The TPU composition can be used to make a fiber reinforced composite in an RTM-type process. The cured thermoplastic matrix has high mechanical properties but still allows for post-cure modification of the moulded part.

EtoxBisF

Ethoxylated Bisphenol F

Steam-Treated Polyisocyanurate: Take Two

Title: PROCESS FOR MAKING URETHANE-ISOCYANURATES

 Number/Link:WO2015/006391

Applicant/Assignee: Dow

Publication date: 15-01-2015

Gist”: Treating PUR-PIR with hot water at superatmospheric pressure results in a Tg increase.

Why it is interesting: This is exactly the same invention as discussed a while ago on this blog: WO2014/160616 . But, apart from the title, the application has been completely re-written by another agent and filed less then 4 months  after the first one. The only difference in the claims appears to be that the temperature and index ranges are taken a bit wider and that filled polyols and polyester polyols are claimed separately.  Very strange.  Is it possible that they forgot they already filed this?

Isocyanurate group

Isocyanurate group