Sound Absorbing PU-PA Foams

Title: THERMOFORMABLE RIGID POLYURETHANE-POLYAMIDE FOAM

 Number/Link: US2014/058005

Applicant/Assignee: BASF

Publication date: 27-2-2014

Gist”: Rigid, open-celled and thermoformable polyurethane-polyamide foams are produced using short chain di-acids as both chain extender and blowing agent.

Why it is interesting: The reaction of a carboxylic acid group with an isocyanate group results in a mixed anhydride, which after releasing carbon dioxide forms an amide. Because the reaction is relatively sluggish a  Lewis base catalyst is used, e.g. N-methylimidazole. In this case a rigid foam-forming formulation based on MDI and (pref.) polyether polyols is further reacted with short chain diacids like azelaic- or glutaric acid.  The examples show foam densities of less than 30 kg/m³ without the use of water.  The foams are open celled with high air flow and with a Tg of around 90°C, making them thermoformable.  This type of foams is used as acoustic bonnet- en roofliners in the automotive industry.

Azelaic Acid

Azelaic Acid

Unique Type of Polyurethane Flexible Foam to Reduce Tyre Noise

Title: TYRE, THE INNER WALL OF WHICH HAS A LAYER OF SPECIFIC POLYURETHANE FOAM

 Number/Link: WO2013/182477 (French)

Applicant/Assignee: Michelin

Publication date: 12-12-2013

Gist”: A layer of flex foam is used to reduce cavity noise in car tyres, the foam being prepared form high EO polyol and 4,4′ MDI.

Why it is interesting: An important component of the noise produced by driving vehicules is attributed to resonances in the tyre cavities. It is know that this noise can be reduced by (partly) filling the tyre cavity with PU foam, but the foams are difficult to apply, add too much weight and do not show enough sound absorption. According to this invention these problems can be solved by adhering a layer of a specific flexible foam to the inside of the tire.  The foam has a low density (30 to 60 kg/m³), and absorbs sound at the correct frequency for cavity resonances (190-230Hz).  It is prepared from a prepolymer based on a  70-90% EO polyol and 4.4′ MDI, which is mixed with water and catalyst.  The reacting mixture is poured into a spinning tyre where it cures and adheres to the inside of the cavity.
This foam -inlcuding the prepolymer- was actually invented by myself in 1991: EP547765

Cross-section of foam-lined tire according to the invention.

Cross-section of foam-lined tire according to the invention.

Flexible Foams containing Polyurethane Phase Change Gels

Title: Polyurethane Gel-Like Polymers, Methods and Use in Flexible Foams  

 Number/Link: US2013/0296449

Applicant/Assignee: PETERSON CHEMICAL TECHNOLOGY

Publication date: 07-11-2013

Gist”:   “Polyurethane phase change gels” prepared from polyurethane gels and conventional PCMs are incorporated into polyurethane or latex flexible foams to improve thermal comfort.

Why it is interesting: This application is closely related to the application discussed in the previous post but instead of a plasticized styrenic triblock copolymer, now a polyurethane gel is used. The PU gel is produced from conventional raw materials at low NCO-index (about 60%) together with plasticizers.

A Polyurethane Gel

A Polyurethane Gel

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