Incorporating “Phase Change Gels” into Flexible Foams for Improved Thermal Comfort

Title: Thermal Storage Gelatinous Triblock Copolymer Elastomer Particles in Polyurethane Flexible Foams

 Number/Link: US2013/295371

Applicant/Assignee: PETERSON CHEMICAL TECHNOLOGY

Publication date: 07-11-2013

Gist”:  Particles of  “phase change gels” prepared from plasticized styrenic TPEs and conventional PCMs are incorporated into polyurethane or latex flexible foams

Why it is interesting: A conventional phase change material (PCM) selected from alkanes, PEGs, hydrated salts ect. with a transition temperature between 20 and 35°C is melt-blended with a plasticized styrenic triblock copolymer like SBS, SIS, SEBS etc. to form a “phase change gel”. The gel is then comminuted and added to a flexible foam forming composition in an amount of about 30 pphp. The resulting foams have an increased thermal conductivity which together with the temperature buffering properties of the PCM improves thermal comfort. The flexible foams are useful in application such as matresses, pillows, automotive cushioning, shoe inserts, medical foams and the like. In my opinion especially useful for viscoleastic (“memory”) foams which are known to suffer from thermal discomfort problems.

Effect of "gel PCM" on heating rate of flexible foam according to the invention.

Effect of “gel PCM” on heating rate of flexible foam according to the invention.

Sulfur Containing Polyurethane Elastomers for Tires and “Tweels”

Title: Polyurethane

 Number/Link: US2013/0287982

Applicant/Assignee: Michelin

Publication date: 31-10-2013  (priority PCT/FR)

Gist”: Use of dithiodiols or dithiodiamines in polyurethane elastomer formulations for improved adhesion to metal.

Why it is interesting: The current invention relates to polyurethane elastomers containing a chain extender mixture consisting of a conventional chain extender (e.g. butandiol) and 1-30% (of the total chain extender) of an S-S bridge containing diol or diamine like 2,2′-dithiodiethanol or 4,4′-dithiodianiline. The resulting polyurethane reportedly shows an increased bonding strength  to metal, which can be even more enhanced by adding elemental sulfur and conventional sulfur-containing rubber-curing accelerators like dithiocarbamates, thiurams, thiazoles etc. (as well known in the art of rubber vulcanization). The resulting polyurethanes are useful for the production of metal strand-reinforced composites like tires and ‘tweels’ (tweel=tire+wheel  see http://michelintweel.com/index.html).

Michelin "tweel"

Michelin “tweel”

Very Tough Polyurethane Elastomers Based on a Novel Type of Polyester Polyol

Title: POLYESTER POLYOL FOR USE IN POLYURETHANE

 Number/Link: WO2013/156450

Applicant/Assignee: Purac Biochem

Publication date: 24-10-2013

Gist”: Tough polyurethane elastomers can be prepared from polyester polyols based on dimer acid and lactide oligomers.

Why it is interesting: The invention claims a new type of ABA polyester polyol where A is a hydrophilic lactide oligomer and B is a hydrophobic dimer diacid initiator. The lactide ologimers can be produced by ring-opening polymerization of cyclic lactide and preferably contain between 4 and 16 lactoyl units.  The dimer diacid is prepared by dimerizing unsaturated C12 to C22 fatty acids, preferably linoleic or linolenic acid. The molecular weight of the polyester polyol is preferably between 1000 and 3500 dalton. Solid polyurethane elastomers prepared from this type of polyols reportedly have much improved toughness and other mechanical properties.

Example of a Dimer Acid

Example of a Dimer Acid

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