Flexible Foams containing Polyurethane Phase Change Gels

Title: Polyurethane Gel-Like Polymers, Methods and Use in Flexible Foams  

 Number/Link: US2013/0296449

Applicant/Assignee: PETERSON CHEMICAL TECHNOLOGY

Publication date: 07-11-2013

Gist”:   “Polyurethane phase change gels” prepared from polyurethane gels and conventional PCMs are incorporated into polyurethane or latex flexible foams to improve thermal comfort.

Why it is interesting: This application is closely related to the application discussed in the previous post but instead of a plasticized styrenic triblock copolymer, now a polyurethane gel is used. The PU gel is produced from conventional raw materials at low NCO-index (about 60%) together with plasticizers.

A Polyurethane Gel

A Polyurethane Gel

Incorporating “Phase Change Gels” into Flexible Foams for Improved Thermal Comfort

Title: Thermal Storage Gelatinous Triblock Copolymer Elastomer Particles in Polyurethane Flexible Foams

 Number/Link: US2013/295371

Applicant/Assignee: PETERSON CHEMICAL TECHNOLOGY

Publication date: 07-11-2013

Gist”:  Particles of  “phase change gels” prepared from plasticized styrenic TPEs and conventional PCMs are incorporated into polyurethane or latex flexible foams

Why it is interesting: A conventional phase change material (PCM) selected from alkanes, PEGs, hydrated salts ect. with a transition temperature between 20 and 35°C is melt-blended with a plasticized styrenic triblock copolymer like SBS, SIS, SEBS etc. to form a “phase change gel”. The gel is then comminuted and added to a flexible foam forming composition in an amount of about 30 pphp. The resulting foams have an increased thermal conductivity which together with the temperature buffering properties of the PCM improves thermal comfort. The flexible foams are useful in application such as matresses, pillows, automotive cushioning, shoe inserts, medical foams and the like. In my opinion especially useful for viscoleastic (“memory”) foams which are known to suffer from thermal discomfort problems.

Effect of "gel PCM" on heating rate of flexible foam according to the invention.

Effect of “gel PCM” on heating rate of flexible foam according to the invention.

Over-Indexed and Crosslinkable Thermoplastic Polyurethane

Title: METHOD FOR MAKING OVER-INDEXED THERMOPLASTIC POLYURETHANE ELASTOMER PRECURSOR AND THERMOPLASTIC POLYURETHANE ELASTOMER MADE FROM THE PRECURSOR

 Patent Number & Link: WO2013/103633

Applicant/Assignee: Nike

Publication date: 11-07-2013

Gist”: A TPU is produced at an NCO index of about 110 comprising an unsaturated chain extender .  The material can be injection moulded and subsequently cured with moisture and free radical polymerization.

Why it is interesting: A thermoplastic PU ‘precursor’ is prepared by reactive extrusion of  a polyol (e.g. a 2000MW polytetramethylene ether glycol), an unsaturated chain extender (e.g. trimethylolpropane monoallyl ether – TMPME), optional additives and MDI at an NCO index of 110 to 115 (preferred). After drying, the resulting pellets can be injection- or compression moulded and then cured by moisture and by heat or UV radiation. The resulting PU-polyurea is claimed to have improved toughness, durability and ‘scuff resistance’ compared to conventional TPUs.  The material appears to have been developed for the golf ball industry.  Nike has filed at least two related ‘golf ball patents’: WO2013/103673 and WO2013/103669.

TMPME: unsaturated chain extender used in the invention

TMPME: unsaturated chain extender used in the invention

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