Flexible Foams containing Polyurethane Phase Change Gels

Title: Polyurethane Gel-Like Polymers, Methods and Use in Flexible Foams  

 Number/Link: US2013/0296449

Applicant/Assignee: PETERSON CHEMICAL TECHNOLOGY

Publication date: 07-11-2013

Gist”:   “Polyurethane phase change gels” prepared from polyurethane gels and conventional PCMs are incorporated into polyurethane or latex flexible foams to improve thermal comfort.

Why it is interesting: This application is closely related to the application discussed in the previous post but instead of a plasticized styrenic triblock copolymer, now a polyurethane gel is used. The PU gel is produced from conventional raw materials at low NCO-index (about 60%) together with plasticizers.

A Polyurethane Gel

A Polyurethane Gel

Incorporating “Phase Change Gels” into Flexible Foams for Improved Thermal Comfort

Title: Thermal Storage Gelatinous Triblock Copolymer Elastomer Particles in Polyurethane Flexible Foams

 Number/Link: US2013/295371

Applicant/Assignee: PETERSON CHEMICAL TECHNOLOGY

Publication date: 07-11-2013

Gist”:  Particles of  “phase change gels” prepared from plasticized styrenic TPEs and conventional PCMs are incorporated into polyurethane or latex flexible foams

Why it is interesting: A conventional phase change material (PCM) selected from alkanes, PEGs, hydrated salts ect. with a transition temperature between 20 and 35°C is melt-blended with a plasticized styrenic triblock copolymer like SBS, SIS, SEBS etc. to form a “phase change gel”. The gel is then comminuted and added to a flexible foam forming composition in an amount of about 30 pphp. The resulting foams have an increased thermal conductivity which together with the temperature buffering properties of the PCM improves thermal comfort. The flexible foams are useful in application such as matresses, pillows, automotive cushioning, shoe inserts, medical foams and the like. In my opinion especially useful for viscoleastic (“memory”) foams which are known to suffer from thermal discomfort problems.

Effect of "gel PCM" on heating rate of flexible foam according to the invention.

Effect of “gel PCM” on heating rate of flexible foam according to the invention.

Controlling the Tg of Viscoelastic Flexible Foams

Title: ADDITIVE FOR ADJUSTING THE GLASS TRANSITION TEMPERATURE OF VISCO-ELASTIC POLYURETHANE SOFT FOAMS

 Number/Link: WO2013/131710

Applicant/Assignee: Evonik

Publication date: 12-09-2013 (German)

Gist”: Use of the di-salt of malic acid to fine-tune the Tg of visco flex foams.

Why it is interesting: The comfort properties of viscoelastic (“memory”) foams are to a large extend controlled by the glass transition temperature of the softblock, which in turn is controlled by NCO index, softblock molecular weight, crosslink density etc. Changing these parameters can be complex however because other properties -like airflow- are affected as well. This invention teaches the surprising effect of the di-sodium-salt of malic acid (hydroxybutanedioic acid) on the Tg of these foams. Apparently a small amount of the compound has a large effect on the Tg and can therefore be used to adjust the Tg without affecting other properties to a large extend.  E.g. about 0.1 php of the salt drops the Tg with 5.5°C, by comparison 0.1 php butanol lowers the Tg only by 0.3°C.

Malic Acid

Malic Acid

  • Pages

  • Categories

  • Enter your email address to follow this blog and receive notifications of new posts by email.

    Join 259 other subscribers
  • Follow Innovation in PU on Twitter