Incorporating “Phase Change Gels” into Flexible Foams for Improved Thermal Comfort

Title: Thermal Storage Gelatinous Triblock Copolymer Elastomer Particles in Polyurethane Flexible Foams

 Number/Link: US2013/295371

Applicant/Assignee: PETERSON CHEMICAL TECHNOLOGY

Publication date: 07-11-2013

Gist”:  Particles of  “phase change gels” prepared from plasticized styrenic TPEs and conventional PCMs are incorporated into polyurethane or latex flexible foams

Why it is interesting: A conventional phase change material (PCM) selected from alkanes, PEGs, hydrated salts ect. with a transition temperature between 20 and 35°C is melt-blended with a plasticized styrenic triblock copolymer like SBS, SIS, SEBS etc. to form a “phase change gel”. The gel is then comminuted and added to a flexible foam forming composition in an amount of about 30 pphp. The resulting foams have an increased thermal conductivity which together with the temperature buffering properties of the PCM improves thermal comfort. The flexible foams are useful in application such as matresses, pillows, automotive cushioning, shoe inserts, medical foams and the like. In my opinion especially useful for viscoleastic (“memory”) foams which are known to suffer from thermal discomfort problems.

Effect of "gel PCM" on heating rate of flexible foam according to the invention.

Effect of “gel PCM” on heating rate of flexible foam according to the invention.

Sulfur Containing Polyurethane Elastomers for Tires and “Tweels”

Title: Polyurethane

 Number/Link: US2013/0287982

Applicant/Assignee: Michelin

Publication date: 31-10-2013  (priority PCT/FR)

Gist”: Use of dithiodiols or dithiodiamines in polyurethane elastomer formulations for improved adhesion to metal.

Why it is interesting: The current invention relates to polyurethane elastomers containing a chain extender mixture consisting of a conventional chain extender (e.g. butandiol) and 1-30% (of the total chain extender) of an S-S bridge containing diol or diamine like 2,2′-dithiodiethanol or 4,4′-dithiodianiline. The resulting polyurethane reportedly shows an increased bonding strength  to metal, which can be even more enhanced by adding elemental sulfur and conventional sulfur-containing rubber-curing accelerators like dithiocarbamates, thiurams, thiazoles etc. (as well known in the art of rubber vulcanization). The resulting polyurethanes are useful for the production of metal strand-reinforced composites like tires and ‘tweels’ (tweel=tire+wheel  see http://michelintweel.com/index.html).

Michelin "tweel"

Michelin “tweel”

Flexible Polyurethane Foams for Thinner Car Seats

Title: CHEMICAL COMPOSITION FOR OBTAINING POLYURETHANE

 Number/Link: WO2013/050639 (Spanish)

Applicant/Assignee: CENTRO TECNOLÓGICO DE GRUPO COPO,

Publication date: 10-04-2012

Gist”: Use of 1,5-pentanediol in flexible foam formulations results in foams with correct comfort properties to allow for thinner car seats.

Why it is interesting: About 2 pphp of 1,5 pentanediol is used together with a  mixture of MDI monomers and a  conventional flexible foam formulation to produce a 55kg/m3 foam with supposedly the correct comfort properties (hardness, hystersis loss, vibration damping  etc.) for a thinner car seat.  While the use of chain extenders is rare in flexible foams, it may very well make sense in somewhat higher-density systems. The first claim of this application however covers much more than flexible foam and will most probably not get granted as such.

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