Hydrophobic Coatings from BO Polyols

Title: POLYURETHANE ENCAPSULATE

 Number/Link: WO2014/176390

Applicant/Assignee: Dow

Publication date: 30-10-2014

Gist”: Use of polybutyleneoxide polyols for hydrophobic encapsulants.

Why it is interesting: The encapsulation of water soluble compounds for controlled release, like e.g. plant nutrients and fertilizers, requires a relatively hydrophobic coating.  Often this is accomplished with polyurethane coatings to which hydrophic compounds are added such as castor oil derivatives. These additives can however have a deleterious effect on other coating properties.  According to this invention encapsulation coatings with good mechanical properties and improved water absorption and water vapour transmission properties can be prepared from polybutyleneoxide triols and polymeric MDI without the need for other additives.

Butylene oxide

Butylene oxide

Renewable Polyurea from Lysinol

Title: NEW POLYMERS DERIVED FROM RENEWABLY RESOURCED LYSINOL

 Number/Link: US2014/275311

Applicant/Assignee: Du Pont

Publication date: 18-09-2014

Gist”: Use of lysinol as renewable monomer for nitrogen-containing polymers including polyurea.

Why it is interesting: Lysinol or 2,5-diamino-1-hexanol is an amino alcohol derived from the amino acid lysine by  hydrogenation.  Lysine itself is produced by fermentation from sugars.  Annual production of lysine is apparently in excess of 1 million tonnes and its derivative lysinol is therefore considered as a potentially interesting biorenenawable monomer for a number of nitrogen-containing polymers. This patent application claims lysinol-based polyamides, polyimides, polyureas and “urethane crosslinked” polyureas including foams. In the examples urethane-polyureas are produced by reacting lysinol with hexamethylenediisocyanate using DABCO as catalyst.

Preparation of the two lysionol enantiomers from lysine.

Preparation of the two lysinol enantiomers from lysine.

Bio-Renewable Thermoplastic Polyurethanes

Title: HOMOGENEOUS EXTRUDED ARTICLES MADE FROM THERMOPLASTICALLY PROCESSABLE POLYURETHANES BASED ON POLYESTER DIOLS FORMED FROM SUCCINIC ACID AND 1,3-PROPANEDIOL

 Number/Link: US2014/0256902

Applicant/Assignee: Bayer

Publication date: 11-09-2014 (priority PCT)

Gist”: TPU based on polyester diols prepared from succinic acid and propandiol

Why it is interesting: The use of biorenewable raw materials is no longer a curiosity in polyurethane production. Especially natural oil-based polyols are currently fashionable in newly developed products.  These ‘NOPs’ are however not very suitable for the production of thermoplastic polyurethanes.  According to the current invention (partly) bio-renewable TPUs can be produced from polyester diols based on succinic acid and 1,3-propanediol. Both these monomers can be produced by fermentation of carbohydrates. 1,3-propanediol is produced on industrial scale by DuPont through fermentation of corn syrup using genetically modified E.Coli bacteria (“Bio-PDO”). In the examples PDO-succinate polyester diols with MW from 1000 to 2000 are used together with 4,4′-MDI and 1,4-butanediol to produce TPUs with shore hardness ranging from 85 to 94A and Tg’s from -18 to +11°C.

Succinic acid or butanedioic acid.

Succinic acid or butanedioic acid.

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