Novel Polyurethane Gels


 Number/Link: W016/036786

Applicant/Assignee: Dow

Publication date: 10-03-2016

Gist”: PU gels are made from MDI prepolymer, high EO polyol and some diamine at low NCO index.

Why it is interesting: Polyurethane gels are well known and are sometimes used in comfort cushioning as layers or dispersed as particles in e.g. viscoelastic matresses. According to this invention plasticizer-free gels can be made by reacting a slightly branched, low NCO prepolymer ( based on 2,4′ and 4,4′ MDI and a high EO polyol), with a large amount of high EO polyol (triol or higher) and some amine-ended low mole-weight diol.
Although the material is said to be ‘plasticizer-free’not all of the polyol will be reacted at low NCO index.  However, because of its high polarity, the unreacted polyol will probably not leach.

A Polyurethane Gel

A Polyurethane Gel


PU Rigid Foams with very Small Cell Size


 Number/Link: WO2015/109488

Applicant/Assignee: Dow

Publication date: 30-07-2015

Gist”: Rigid foams are blown with CO2 under pressure

Why it is interesting: It is known that the thermal conductivity of conventional rigid polyurethane foams can be most efficiently improved by reducing the conductivity contribution of the gas present in the foam cells. This, in turn, can be achieved by reducing the gas pressure, by using ‘heavy’ blowing agents or by reducing the average cell size.  The current application discloses rigid PU foams having cell sizes small enough to achieve a thermal conductivity of less than 16 mW/m.K without the need for a strong vacuum or special blowing agents. This is achieved by first saturating the polyol formulation with CO2 under pressure, then adding the isocyanate and increasing the pressure for a set amount of time and finally releasing the pressure to allow the material to expand. Examples are given using a pressure of 7 MPa at 40°C for 30 minutes to saturate the polyol, and a pressure of 10 MPa for up to about 10 minutes after addition of the isocyanate.  Foams with average cell sizes of 8 to 70 μm and porosities of up to 90% are obtained at densities of about 250 to about 300 kg/m³.  Oddly enough no thermal conductivity (λ) values are given.

Rigid polyurethane insulation foams (Wikimedia)

Rigid polyurethane insulation foams (Wikimedia)


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