Incorporating “Phase Change Gels” into Flexible Foams for Improved Thermal Comfort

Title: Thermal Storage Gelatinous Triblock Copolymer Elastomer Particles in Polyurethane Flexible Foams

 Number/Link: US2013/295371

Applicant/Assignee: PETERSON CHEMICAL TECHNOLOGY

Publication date: 07-11-2013

Gist”:  Particles of  “phase change gels” prepared from plasticized styrenic TPEs and conventional PCMs are incorporated into polyurethane or latex flexible foams

Why it is interesting: A conventional phase change material (PCM) selected from alkanes, PEGs, hydrated salts ect. with a transition temperature between 20 and 35°C is melt-blended with a plasticized styrenic triblock copolymer like SBS, SIS, SEBS etc. to form a “phase change gel”. The gel is then comminuted and added to a flexible foam forming composition in an amount of about 30 pphp. The resulting foams have an increased thermal conductivity which together with the temperature buffering properties of the PCM improves thermal comfort. The flexible foams are useful in application such as matresses, pillows, automotive cushioning, shoe inserts, medical foams and the like. In my opinion especially useful for viscoleastic (“memory”) foams which are known to suffer from thermal discomfort problems.

Effect of "gel PCM" on heating rate of flexible foam according to the invention.

Effect of “gel PCM” on heating rate of flexible foam according to the invention.

Rigid Polyurethane Foam Containing Expandable Particles

Title: Highly Insulating Polyurethane Foam and Method for Manufacturing Same

 Number/Link:US2013/0150470

Applicant/Assignee: Cheil Industries

Publication date: 13-06-2013 (priority PCT/KR)

Gist”: Rigid foams comprising thermally expandable particles which penetrate cell walls and which are covered with an infrared absorbing filler show improved insulation properties.

Why it is interesting: The invention claims to improve insulation properties of rigid foams by including about 5% (on the total resin) of organic thermally expandable particles with a diameter of about 5 μm before expansion and of about 50 μm after expansion. A filler chosen from carbon black, graphite, carbon nanotubes and the like is added as well. After the foam is formed the expanded particles penetrate the cell walls, are supposedly covered with the filler and are believed to reduce the radiation component of the thermal conductivity. Foam properties given in the examples show a density of about 35 kg/m³ with a thermal conductivity of about 0.0160 kcal/m.h.ºC (or about 0.019 W/m.K if I converted this correctly).

fig 2 form the patent.  Large circles are expanded particles, smaal circles is filler.

Fig 2 form the patent: large circles are the expanded particles, the small circles represent the filler.

Polyurethane OCF Systems with Low Monomeric Isocyanate Content

Title: IMPROVED POLYURETHANE FOAM COMPOSITION

 Number/Link: WO2013/072380

Applicant/Assignee: SOUDAL

Publication date: 23-05-2013

Gist”: Use of mono-alcohols to reduce monomeric isocyanate content in OCF systems.

Why it is interesting: OCF , or one component foam (or froth) systems are isocyanate ended prepolymers, mixed with organic blowing agents and other additives like catalysts. They are often prepared directly into pressure cans and are mostly used in construction as adhesives and sealants.  Curing happens by reaction with ambient moisture. Recent changes in legislation has forced OCF producers to drop the amount of free monomeric isocyanate in their systems.  In this invention OCF systems with less than 1% free monomeric MDI are produced by reacting a conventional diol, a polymeric/monomeric MDI mixture and a relatively low MW monol (2-ethyl-hexanol in the examples).  The monol allows to produce prepolymers with low NCO content and low free MDI by preventing chain extension and therefore avoiding extreme viscosity build-up.

OCF system in pressure can.

OCF system in pressure can.

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