Composite Polyurethane-Polystyrene Thermal Insulation Foams

Title:  METHOD FOR PRODUCTION OF HEAT INSULATING COMPOSITE MATERIALS AND HEAT INSULATING COMPOSITEMATERIAL PRODUCED THEREBY

 Number/Link: WO2013/021324

Applicant/Assignee: HIT KONSULTING

Publication date: 14-02-2013

Gist”: Expandable polystyrene beads are added to rigid PUR or PIR foam system.

Why it is interesting: EPS beads with a softening temperature of 80-90°C are added to the isocyanate stream in an amount of 15-60% w/w to the total system. The exotherm has to be exactly right to fully expand and not degrade the EPS, and is controlled by the ratio PU/EPS.  This idea is not new, but it remains an interesting route to cheap insulation. The claim is relatively narrow so could get granted imo.

Expandable Polystyrene (Wikimedia)

Expandable Polystyrene (Wikimedia)

Insulating Elastomer-Aerogel Composites

Title: INSULATING MATERIAL COMPRISING AN ELASTOMER IMPREGNATED WITH AEROGEL-BASE

 Number/Link:  US2013022769

Applicant/Assignee: UNIV MEMPHIS

Publication date: 24-01-2013

Gist”: Elastomeric material containing aerogel ‘bodies’, useful for heat insulation.

Why it is interesting:  The elastomeric matrix material can be any kind of thermoset or thermoplastic rubber, including polyurethanes but RTV silicones are preferred. The aerogels can be organic, inorganic or hybrid, but are preferably polyurea-crosslinked silicas of any geometrical shape,  preferably 1-5mm in size with an aerogel:polymer ratio of 15:100 to 200:100 (w/w). Both insulation and mechanical properties compare favourably to ASPEN aerogel blankets. Useful for insulation of cryogenic fuel tanks a.o.

Space shuttle with PU insulated cryogenic fuel tank.

Space shuttle with PU insulated cryogenic fuel tank. (Wikimedia)

Reticulated Foam-Fiber Composites

Title: A RETICULATED OPEN-CELL FOAM MODIFIED BY FIBERS EXTENDING ACROSS AND BETWEEN THE CELLS OF SAID FOAM AND PREPARATION METHODS THEREOF

 Number/Link: WO2013010245

Applicant/Assignee: EPIC VENTURES INC

Publication date: 24-01-2013

Gist”: Reticulated polyurethane foams containing fibers extending across and between cells. The foams can then be impregnated with metals (Nickel) and the polymer pyrolized resulting in porous metal structures useful in batteries.

Why it is interesting:  Reticulated foams (i.e. foams consisting only of a ‘strut skeleton’ and having no cell membranes) are well known, but the application is not clear about which process is to be used in this case, neither does it provide an example of a formulation. Chopped metal, glass or carbon  fibers are added to the foam-forming composition supposedly ‘resulting’ in a reticulated foam/fibre composite.  The fibers extend over about 5 cell diameters (e.g. 1-1.5 mm ) and are used in 10-30% v/v. Foams like this could be interesting for filtration, heat exchange and especially sound absorption -with  the fibers adding extra “tortuosity”. The patent is mainly concerned with the subsequent production of metal foams for use in batteries e.g.

Reticulated Foams with Fibers

Reticulated Foam with Fibers

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