Patent Title: THERMOPLASTIC PUR WITH HIGH TG FOR REACTION TRANSFER MOLDING (RTM)
Number/Link: WO2018/050433
Applicant/Assignee: Henkel
Publication date: 22 march 2018
“Gist”: High Tg TPU from polycyclic diols
Why it is interesting: The invention is about thermoplastic polyurethanes with high Tg and high stiffness that are useful for fiber-reinforced composites made by (reactive) resin transfer moulding. The TPU is prepared from an isocyanate, a conventional diol chain extender and at least 25% (w/w) of a bridged- fused- or spiro- polycyclic diol. In the examples MDI is reacted with 1,2-propanediol or 2,3-butandiol and 4,8-bis(hydroxymethyl)tricyclo[5.2.1.02,6]decane. The resulting TPUs show a Tg of more than 135°C.

4,8-bis(hydroxymethyl)tricyclo[5.2.1.02,6]decane