Insulating Polyurethane Foams Containing Impregnated Aerogel Particles

Title: METHOD FOR MAKING ORGANIC FOAM COMPOSITES CONTAINING AEROGEL PARTICLES

 Number/Link: WO2013000861

Applicant/Assignee: Dow

Publication date: 3-01-2013

Gist”: Polyurethane or polyisocyanurate (or -less preferred- extruded foams like EPS foams) are produced in the presence of aerogel particles impregnated with blowing agents resulting in composite foams with exceptional insulation properties.

Why it is interesting: The blowing agent evaporates during the reaction (or extrusion),expands the foam and prevents the aerogel particles of losing their porosity and low density.  Already 0.1% w/w of the particles is claimed to have a significant impact on insulation properties.  In the examples an HFC blowing agent is used together with aerogel particles with an average size of about 1mm.
It appears that composites of aerogels together with PU or PIR, but also with PS and rockwool e.g. are becoming an ever more important trend in insulation.

Aerogel (Wikipedia)

Aerogel (Wikipedia)

Polyurea xerogel

Title:  PROCESS FOR PRODUCING FLAME-RETARDANT POROUS MATERIALS BASED ON POLYUREA

Number:  US2012235070

 Publication date:  20-9-2012

Applicant/Assignee: BASF

Gist: polyfunctional isocyanate and polyfunctional amine are reacted in organic solvent containing soluble flame ratardant.  The solvent is then removed, under subcritical conditions, resulting in a self-standing porous material..

Why it is interesting:  Since a few years there is a surge of BASF patent applications on microporous/nanoporous materials for insulation, and this case is probably only one of many to follow. It appears BASF is taking the lead in this highly promising field for PU insulation.

Insulation foam with bimodal cell size distribution

Title:  METHOD FOR PRODUCING A POLYURETHANE FOAM AND POLYURETHANE FOAM OBTAINABLE THEREBY

Number: US2012238655

Publication date: 20-9-2012

Applicant/Assignee: Bayer IP

Gist: isocyanate and polyol reacted together with specific surfactante and blowing agent in supercritical state.

Why it is interesting: Heat insulation is a ‘hot’ topic in polyurethane research.  One way to improve insulation is to reduce cell size to nano-scale. This material is interesting because it combines both micron-scale cells as nano-scale cells which is claimed to result in improved insulation as well as mechanical properties.

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