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Classic PU Patent of the Month: ICI on MDI Prepolymers and “Cold Cure” Flexible Foams (1978)

November 17, 2014 16:39

Title: Liquid polyisocyanate compositions

 Number/Link:  EP10850

Applicant/Assignee: Imperial Chemical Industries

Publication date: 14-05-1980

Gist”: Liquid compositions from 2,4’/4,4′-MDI  prepolymers and polymeric MDI.

Why it is interesting: The first polyurethane flexible foams were all based on toluene diisocyanate (TDI).  Other commericially available isocyanates like “pure MDI”  (4,4’/ 2,4′- diphenylmethane diisocyanates mixtures) and “crude MDI” (mixtures of MDI and its higher homologues) were not suited for flexible foam production: the former because of it’s high crystallinity and therefore too high melting point and the latter because of its too high functionality.  This classic invention solved the problem by prepolymerizing  a 2,4’/4,4′-MDI mixture with a “flexible” polyol to an NCO content of 8 to 26% and then adding 10-50% of crude MDI to obtain a liquid composition. These liquid MDI compositions allowed the production of cold cure moulded flexible foams and the first MDI-based car seat cushions.

Cold cure moulded car seat cushions

Cold cure moulded car seat cushions

Posted by Gerhard Bleys

Categories: Classic PU Patent of the month, Flexible Foams, Isocyanates and Prepolymers

Tags: , , , , ,

One Response to “Classic PU Patent of the Month: ICI on MDI Prepolymers and “Cold Cure” Flexible Foams (1978)”

  1. […] in unstable foaming. The problem was eventually solved by using prepolymers and polymeric MDI, as mentioned before.  More than 10 years later it was shown that it is possible to make flexible foams with […]

    By Classic PU Patent of the Month: ICI on “High EO – Pure MDI” Flexible Foams (1991) | Innovation in Polyurethanes on January 22, 2016 at 15:19

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