Polyurethane Ionomers and the “Golf Ball Conundrum”

Title: REINFORCING IONOMERIC MATERIALS USING MULTI-FUNCTIONAL MODIFIER WITH ACID FUNCTIONAL GROUP

 Number/Link: US2012289364

Applicant/Assignee: TAYLOR MADE GOLF CO

Publication date: 11-11-2012

Gist”: Use of carboxyl group-containing PU ionomers in golf ball covers.

Why it is interesting: It is claimed that certain PU ionomers have advantages over other ionomers for use in golf ball covers. In many golf balls SURLYN(TM) is used as the material of choice, Dupont even has a complete range of resins just for golf balls.
But what is really interesting – or at least remarkable- is the sheer number of golf ball patent applications published each year. More than 7500 were published during the last 10 year (see graph).  About half of these applications are from the US, the rest mostly from the East:  Japan, Korea and since 2005 also from China.

All these patents are about balls to be hit with a stick…  it makes one wonder what there still is left to be improved..

Polyurethane Particles Produced Without Isocyanates

Title: POLYHYDROXYURETHANE MICROPARTICLES, AND PROCESS FOR PRODUCING SAME

 Number/Link: WO2012150684  (in Japanese)

 Applicant/Assignee: DAINICHISEIKA COLOR CHEM

Publication date: 8-11-2012

Gist”: Polyhydroxyurethane microparticles produced form cyclic carbonates and amines. 

Why it is interesting: For a number of years non-isocyanate (hydroxy-)polyurethanes have been promoted by Oleg Figovsky (a.o.) without much success. However now and then this chemistry pops up again, usually related to coating systems.

“Proppants” for “Fracking”.

Numbers/Links:  WO2012151260 WO2012151091 US20120283153 

Applicants/Assignees: PREFERRED UNLIMITED and  BASF,

Gist”: Coating sand particles, using isocyanate containing compositions,  to be used as “proppants” for “fracking”.

Publication dates: all on 8-11-2012

Why it is interesting: The production of  natural gas and oil by hydraulic fracturing or “fracking” has increased exponentially in the last few years and will probably turn the US into the largest oil producer in the world in the near future.  This is big business.  Fracking is done by pumping a slurry of sand, water and a load of chemicals under high pressure into oil containing rocks to produce fractures and release gas and oil. Using sand has the disadvantage of being abrasive to equipment and causing ‘back flow’. Coating the sand makes it better flowing, less abrasive and more adhesive to rock.  The BASF case e.g. uses waterglass together with isocyanate as a coating composition.

Fracking (Wikimedia)

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